Advances in Chemical Propulsion (auth unkn) [No TOC]

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L. Frenkel. 1995. Thermodynamic properties of pentacycloundecane, C11 H14 . J. Chem. Thermodynamics 27: 707–20. © 2002 by CRC Press LLC Chapter 4 DECOMPOSITION CHEMISTRY OF HIGH-ENERGY-DENSITY FUELS BY FLOW TUBE MASS SPECTROMETRY Z. Li and S. L. Anderson A method is described that allows study of thermal breakdown behavior of organic high-energy-density fuel molecules. In addition to stability vs. temperature results, the distribution of product species as a function of temperature is also determined.

The ranges given show how the flow properties vary as the temperature is raised from 298 and 998 K. The advantage of the microflow tube is that sample consumption is very small. For the work discussed below, the consumption rate varied between ∼ 5 and ∼ 25 µg/s, allowing several hours of experiment time for 20–40 mg of sample. , the average distance that the molecules diffuse during the residence time in the hot zone, was about five times the tube diameter. The molecules diffused back and forth across the tube bore several times during their passage through the hot zone.

G. Bott. 1998. Synthesis, characterization and crystal density modeling of spiropolycyclic oxiranes. Tetrahedron 54:4485–92. 37. , M. J. Friedauer, H. S. Udaykumar, W. Shyy, and A. P. Marchand. 1997. Ignition characteristics of a new high-energy strained fuel in high-speed flows. J. Propulsion Power 13:246–49. © 2002 by CRC Press LLC 38. Kabo, G. , A. A. Kozyro, A. P. Marchand, V. V. Diky, V. V. Simirsky, L. S. Ivashkevich, A. P. Krasulin, V. M. Sevruk, and M. L. Frenkel. 1994. Thermodynamic properties of heptacyclotetradecane, C14 H16 .

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